What is the N-Formylmorpholine?

N-Formylmorpholine is clear yellow liquid, while it's Molecular Formula is C5H9NO2. clear yellow liquid 4-Formylmorpholine has been used in the preparation of:adenine hydrochloride labelled with 14Cterphenyl dialdehyde

What is the CAS number for N-Formylmorpholine?

The CAS number of N-Formylmorpholine is 4394-85-8.

What is N-Formylmorpholine (4394-85-8) used for?

N-Formylmorpholine, also known as 4-Formylmorpholine, is an organic compound that serves as a versatile intermediate in the synthesis of various chemical products. It possesses a formyl group attached to a morpholine ring, which allows it to participate in a range of chemical reactions and form different derivatives. Used in Chemical Industry: N-Formylmorpholine is used as a solvent and extracting agent for aromatics, due to its ability to dissolve and selectively extract aromatic compounds from mixtures. Used in Gas Treatment: N-Formylmorpholine is used as a scrubbing agent for acidic gases, helping to remove harmful acidic components from gas streams, which is crucial for environmental protection and industrial processes. Used in Pharmaceutical Industry: N-Formylmorpholine is used in the preparation of adenine hydrochloride labeled with 14C, a compound used in research and development of pharmaceutical products, particularly in radiolabeling techniques for tracking and studying biological processes. Used in Fine Chemicals Synthesis: N-Formylmorpholine is employed in the synthesis of various fine chemicals, such as 4-(trifluoromethyl)morpholine, 3-alkyl-2-chloro-5,6-dihydrobenzaldehyde, and terphenyl dialdehyde, which have applications in the development of pharmaceuticals, agrochemicals, and other specialty chemicals. Used in Environmental Protection: N-Formylmorpholine plays an important role in the desulfurization of natural gas, synthetic gas, flue gas, and gasoline, contributing to the reduction of sulfur compounds that can cause environmental pollution and acid rain.InChI:InChI=1/C5H9NO2/c7-5-6-1-3-8-4-2-6/h5H,1-4H2

What is the N-Formylmorpholine?

N-Formylmorpholine is clear yellow liquid, while it's Molecular Formula is C5H9NO2. clear yellow liquid 4-Formylmorpholine has been used in the preparation of:adenine hydrochloride labelled with 14Cterphenyl dialdehyde

What is the CAS number for N-Formylmorpholine?

The CAS number of N-Formylmorpholine is 4394-85-8.

What is N-Formylmorpholine (4394-85-8) used for?

N-Formylmorpholine, also known as 4-Formylmorpholine, is an organic compound that serves as a versatile intermediate in the synthesis of various chemical products. It possesses a formyl group attached to a morpholine ring, which allows it to participate in a range of chemical reactions and form different derivatives. Used in Chemical Industry: N-Formylmorpholine is used as a solvent and extracting agent for aromatics, due to its ability to dissolve and selectively extract aromatic compounds from mixtures. Used in Gas Treatment: N-Formylmorpholine is used as a scrubbing agent for acidic gases, helping to remove harmful acidic components from gas streams, which is crucial for environmental protection and industrial processes. Used in Pharmaceutical Industry: N-Formylmorpholine is used in the preparation of adenine hydrochloride labeled with 14C, a compound used in research and development of pharmaceutical products, particularly in radiolabeling techniques for tracking and studying biological processes. Used in Fine Chemicals Synthesis: N-Formylmorpholine is employed in the synthesis of various fine chemicals, such as 4-(trifluoromethyl)morpholine, 3-alkyl-2-chloro-5,6-dihydrobenzaldehyde, and terphenyl dialdehyde, which have applications in the development of pharmaceuticals, agrochemicals, and other specialty chemicals. Used in Environmental Protection: N-Formylmorpholine plays an important role in the desulfurization of natural gas, synthetic gas, flue gas, and gasoline, contributing to the reduction of sulfur compounds that can cause environmental pollution and acid rain.InChI:InChI=1/C5H9NO2/c7-5-6-1-3-8-4-2-6/h5H,1-4H2

Factory supply 4-Formylmorpholine 4394-85-8 with sufficient stock and high standard

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4-Formylmorpholine

ProductNo:350993-cfadf21c-7a3a-4224-a20c-98d16e5393b4

Packing:
CasNo.:4394-85-8

MW:115.132
Purity:>

Content:
MF:C₅H₉NO₂

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Factory supply 4-Formylmorpholine 4394-85-8 with sufficient stock and high standard

Molecular Formula:C5H9NO2
Molecular Weight:115.132
Appearance/Colour:clear yellow liquid
Vapor Pressure:0.0472mmHg at 25°C
Melting Point:23 °C(lit.)
Refractive Index:n20/D 1.485(lit.)
Boiling Point:236.5 °C at 760 mmHg
PKA:-0.75±0.20(Predicted)
Flash Point:107 °C
PSA：29.54000
Density:1.21 g/cm³
LogP:0.04880

N-Formylmorpholine(Cas 4394-85-8) Usage

Synthesis Reference(s)	The Journal of Organic Chemistry, 25, p. 199, 1960 DOI: 10.1021/jo01072a012
Flammability and Explosibility	Nonflammable
General Description	Treatment of 4-formylmorpholine with sulphur tetrafluoride in the presence of potassium fluoride gives 4-(trifluoromethyl)morpholine in excellent yields. 4-Formylmorpholine reacts with series of 2-alkyl-2-cyclohexen-1-ones in the presence of POCl3 to give the corresponding 3-alkyl-2-chloro-5,6-dihydrobenzaldehydes and allylic alcohols (by-product).

InChI:InChI=1/C5H9NO2/c7-5-6-1-3-8-4-2-6/h5H,1-4H2

4394-85-8 Relevant articles

Confirmation by trapping, synthesis, and reactivity of 2,3-dehydro-N-methylmorpholine (DNMM)

Liebner, Falk,Schmid, Peter,Adelw?hrer, Christian,Rosenau, Thomas

, p. 11817 - 11821 (2007)

The elusive 4-methyl-3,4-dihydro-2H-[1,4...

-

Yoshimura et al.

, p. 307 (1973)

-

Nefedov,B.K. et al.

, (1973)

Additive-free selective methylation of secondary amines with formic acid over a Pd/In2O3 catalyst

Benaissa, Idir,Cantat, Thibault,Genre, Caroline,Godou, Timothé,Pinault, Mathieu

, p. 57 - 61 (2022/01/19)

Formic acid is used as the sole carbon a...

Germyliumylidene: A Versatile Low Valent Group 14 Catalyst

Sarkar, Debotra,Dutta, Sayan,Weetman, Catherine,Schubert, Emeric,Koley, Debasis,Inoue, Shigeyoshi

supporting information, p. 13072 - 13078 (2021/08/09)

Bis-NHC stabilized germyliumylidenes [RG...

Solvent-free, Efficient Transamidation of Carboxamides with Amines Catalyzed by Recyclable Sulfated Polyborate Catalyst

Mali, Anil S.,Indalkar, Krishna,Chaturbhuj, Ganesh U.

, p. 369 - 378 (2021/07/26)

Nickel-Catalyzed Amination of Aryl Chlorides with Amides

Li, Jinpeng,Huang, Changyu,Wen, Daheng,Zheng, Qingshu,Tu, Bo,Tu, Tao

supporting information, p. 687 - 691 (2021/01/09)

A nickel-catalyzed amination of aryl chl...

4394-85-8 Process route

: 20099-92-7
1-(4-methoxyphenyl)-2-(4-morpholinyl)ethanone

: 4394-85-8
4-morpholinecarboxaldehyde

: 100-09-4
4-methoxybenzoic acid

Conditions

Conditions	Yield
With TEMPO; oxygen; In acetonitrile; at 50 ℃; for 38h; under 760.051 Torr;	50% 73%

: 794-06-9
α-(N-morpholino)-α-phenylacetophenone

: 110-91-8,99108-56-2
morpholine

: 4394-85-8
4-morpholinecarboxaldehyde

: 1468-28-6
4-benzoylmorpholine

: 100-52-7
benzaldehyde

: 134-81-6
benzil

: 65-85-0,8013-63-6
benzoic acid

Conditions

Conditions	Yield
With oxygen; rose bengal; In water; benzene; Quantum yield; Irradiation; oxidative fragmentation;	56 % Chromat. 12 % Chromat. 10 % Chromat. 10 % Chromat.